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We present results from a new simulation code that accounts for the evolution of the reservoirs of carbon dioxide on Mars, from its early years to the present. We establish a baseline model parameter set that produces results compatible with the present (i.e., Patm?6.5 mbar with permanent CO2 ice cap) for a wide range of initial inventories. We find that the initial inventory of CO2 broadly determines the evolutionary course of the reservoirs of CO2. The reservoirs include the atmosphere, ice cap, adsorbed CO2 in the regolith, and carbonate rocks. We track the evolution of the free inventory: the atmosphere, ice cap and regolith. Simulations begin at 4.53 Gyr before present with a rapid loss of free inventory to space in the early Noachian. Models that assume a relatively small initial inventory (?5 bar) have pronounced minima in the free inventory of CO2 toward the end of the Noachian. Under baseline parameters, initial inventories below ∼4.5 bar result in a catastrophic loss of the free inventory to space. The current free inventory would be then determined by the balance between outgassing, sputtering losses and chemical weathering following the end of the late bombardment. We call these “thin” models. They generically predict small current free inventories in line with expectations of a small present CO2 ice cap. For “thick” models, with initial inventories ?5 bar, a surplus of 300-700 mbar of free CO2 remains during the late-Noachian. The histories of free inventory in time for thick models tend to converge within the last 3.5 Gyr toward a present with an ice cap plus atmospheric inventory of about 100 mbar. For thick models, the convergence is largely due to the effects of chemical weathering, which draws down higher free inventories more rapidly than the low. Thus, thick models have ?450 mbar carbonate reservoirs, while thin models have ?200 mbar. Though both thick and thin scenarios can reproduce the current atmospheric pressure, the thick models imply a relatively large current CO2 ice cap and thin models, little or none. While the sublimation of a massive cap at a high obliquity would create a climate swing of greenhouse warming for thick models, under the thin model, mean temperatures and pressures would be essentially unaffected by increases in obliquity.  相似文献   
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In this work, the factors controlling the formation and preservation of high-pressure mineral assemblages in the metamorphosed orthopyroxene-bearing metagranitoids of the Sandmata Complex, Aravalli-Delhi Mobile Belt (ADMB), northwestern India have been modelled. The rocks range in composition from farsundite through quartz mangerite to opdalite, and with varying K2O, Ca/(Ca + Na)rock and FeOtot + MgO contents. A two stage metamorphic evolution has been recorded in these rocks.
An early hydration event stabilized biotite with or without epidote at the expense of magmatic orthopyroxene and plagioclase. Subsequent high-pressure granulite facies metamorphism (∼15 kbar, ∼800 °C) of these hydrated rocks produced two rock types with contrasting mineralogy and textures. In the non-migmatitic metagranitoids, spectacular garnet ± K-feldspar ± quartz corona was formed around reacting biotite, plagioclase, quartz and/or pyroxene. In contrast, biotite ± epidote melting produced migmatites, containing porphyroblastic garnet incongruent solids and leucosomes.
Applying NCKFMASHTO T–M (H2O) and P–T pseudosection modelling techniques, it is demonstrated that the differential response of these magmatic rocks to high-pressure metamorphism is primarily controlled by the scale of initial hydration. Rocks, which were pervasively hydrated, produced garnetiferous migmatites, while for limited hydration, the same metamorphism formed sub-solidus garnet-bearing coronae. Based on the sequence of mineral assemblage evolution and the mineral compositional zoning features in the two metagranitoids, a clockwise metamorphic P–T path is constrained for the high-pressure metamorphic event. The finding has major implications in formulating geodynamic model of crustal amalgamation in the ADMB.  相似文献   
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Surface morphology and related issues for nuclei of three comets: Halley, Borrelly and Wild 2, are considered in the paper. Joint consideration of publications and results of our analysis of the comets’ images led to conclusions, partly new, partly repeating conclusions published by other researchers. It was found that typical for all three nuclei is the presence of rather flat areas: floors of craters and other depressions, mesas and terraces. This implies that flattening surfaces or planation is a process typical for the comet nuclei. Planation seems to work through the sublimation-driven slope collapse and retreat. This requires effective sublimation so this process should work only when a comet is close to the Sun and if on the nucleus there are starting slopes, steep and high enough to support the “long-distance” avalanching of the collapsing material. If the surface had no starting slopes, then instead of planation, the formation of pitted-and-hilly surfaces should occur. An example of this could be the mottled terrain of the Borelly nucleus. Both ways of the sublimational evolution on the nucleus surface should lead to accumulation of cometary regolith. The thickness of the degassed regolith is not known, but it is obvious that in surface depressions, including the flat-floor ones, it should be larger compared with nondepression areas. This may have implications for the in situ study of comets by the Deep Impact and Rosetta missions.Our morphological analysis puts constraints on the applicability of the popular “rubble-pile comet nucleus” hypothesis (Weissman, 1986. Are cometery nuclei primordial rubble piles? Nature 320, 242-244.). We believe that the rubble pile hypothesis can be applicable to the blocky Halley nucleus. The Borelly and Wild 2 nuclei also could be rubble piles. But in these cases the “rubbles” have to be either smaller than 30-50 m (a requirement to keep lineament geometry close to ideal), or larger than 1-2 km (a requirement to form the rather extended smooth, flat surfaces of mesa tops and crater floors). Another option is that the Borelly and Wild 2 nuclei are not rubble piles.In relation to surface morphology we suggest that three end-member types of the comet nuclei may exist: (1) impact cratered “pristine” bodies, (2) non-cratered fragments of catastrophic disruption, and (3) highly Sun-ablated bodies. In this threefold classification, the Wild 2 nucleus is partially ablated primarily cratered body. Borrelly is significantly ablated and could be either primarily cratered or not-cratered fragment. Halley is certainly partially ablated but with the available images it is difficult to say if remnants of impact craters do exist on it.Recently published observations and early results of analysis of the Tempel 1 nucleus images taken by Deep Impact mission are in agreement with our conclusions on the processes responsible for the Halley, Borrelly and Wild 2 nuclei morphologies. In particular, we have now more grounds to suggest that decrease in crater numbers and increase of the role of smooth flat surfaces in the sequence Wild 2?Tempel 1?Borelli reflects a progress in the sublimational degradation of the nucleus surface during comet passages close to the Sun.  相似文献   
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